Control Self-Assembly of Hydrazide-Based Cyclic Hexamers: In or Out

نویسندگان

  • Yong Yang
  • Fei Huang
  • Chuan-Feng Chen
  • Min Xia
  • Qingyun Cai
  • Fang-Jun Qian
  • Junfeng Xiang
چکیده

By moving the alkoxy group on the spacer from position 5 to position 4 to add another protocol for the algorithm for intermolecular and intramolecular hydrogen bonding interactions, highly regioselectivity of noncovalent synthesis of the hydrazide-based cyclic hexamers was achieved: one out of thirteen possible isomeric cyclic hexamers selectively formed and thus precise control of the two hydrazide units in the cyclic hexamers (in or out) was accomplished.

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عنوان ژورنال:

دوره 3  شماره 

صفحات  -

تاریخ انتشار 2013